Friday, March 21, 2014

What is sugar, Non sugar, Reducing sugar, Non reducing sugar?

Sugar:
  • Substances which are water soluble, crystalline and sweet in taste are called sugar. 
  • All monosaccharides and disaccharides are sugar.
Non sugar:
  • Substances which are water insoluble and amorphous.
  • Polysaccharides are non sugar.
Reducing sugar:
  • They act as reducing agent in alkaline media.
  • Presence of free aldehyde and or ketone functional group is responsible for this property of carbohydrate.
  • All monosaccharides maltose and lactose are reducing sugars.
  • Reducing property of sugar is tested by their ability to 
    • Reduce alkaline CuSO4 solution (Positive Benedict's test)
    • From osazone crystal with phenyl hydrazine
    • Show maturation
Non reducing sugar:
  • They do not contain free aldehyde or ketone as functional group.
  • Their functional groups are usually engaged in glycosidic bond formation
  • Sucrose is non reducing sugar.

What is carbohydrate? Classify Carbohydrate.

Carbohydrate:
The compound which on hydrolysis produces the substances having aldehyde or ketone functional group.

Classification:
1. Monosaccharide or simple sugar.
  • The simplest form of carbohydrate which cannot be hydrolyzed further into further simple form of carbohydrate.
  • These are of 3 to 9 carbons and serve as building blocks of all carbohydrate.
  • Pentoses and Hexoses are the monosaccharides of greatest biological importance.
  • Example: Glucose, Fructose, Galactose, Mannose, Ribose, Ribulose etc.
2. Disaccharide
  • Carbohydrate produced by condensation of two monosaccharide units by glycosidic bond.
  • Sugars that produce two molecules of same or different monosaccharide on hydrolysis.
  • Example: Maltose (Consists of two glucose molecules)
                        Lactose (Consists of one glucose and one galactose)
                       Sucrose (Consists of one glucose and one Fructose)
3. Oligosaccharide
  • Carbohydrate produced by condensation of 3 to 10 monosaccharide units by glycosidic bond.
  • Example: Maltotriose, Raffinose, Blood group substances.
4. Polysaccharide:
  • Polymer of monosaccharide composed of more than 10 monosaccharide units connected by glycosidic bond.
  • Example: Starch, Glycogen, Cellulose, Mucopolysaccharide, Glycoprotein.